In the Danish emission inventories system emissions from industrial processes and product use (IPPU) are treated separately from emissions related to fuel consumption in the industry; these are included in the Energy Sector (Stationary combustion). IPPU emissions in Denmark are divided in seven main groups of sources.

• A. Mineral Industry; includes emissions from cement production, lime production, glass production, production of ceramics, fluegas desulphurisation, mineral wool production, other process uses of soda ash, quarrying & mining, construction & demolition and storage, handling & transport of mineral products. The relevant pollutants are CO₂, SO₂, NMVOC, NH₃, CO, particles (TSP, PM₁₀, PM_2.5), BC, heavy metals (Pb, Cd, As, Cr, Ni, Se, Zn), HCB, PCBs and PDCC/F.

• B. Chemical Industry; includes emissions from production of sulphuric acid (ceased in 1997), nitric acid (ceased in 2004), production of catalysts/fertilizers, pesticides, tar products and other chemical ingredients. The relevant pollutants are CO₂, N₂O, SO₂, NO_x, NMVOC, NH₃, particles (TSP, PM₁₀, PM_2.5), BC and Hg.

• C. Metal Industry; includes emissions from iron foundries, steelworks, magnesium production (ceased in 2000), secondary aluminium production, secondary lead production and gun metal production (red bronze). The relevant pollutants are CO₂, SF₆, SO₂, NO_x, CO, NMVOC, particles (TSP, PM₁₀, PM_2.5), BC, heavy metals (Pb, Cd, Hg, As, Cr, Cu, Ni, Se, Zn), HCB, PCBs and PCDD/F.

• D. Non-Energy Products from Fuels and Solvent Use; includes emissions from solvent use, road paving with asphalt, asphalt roofing, coating applications, dry cleaning, printing, chemical products, urea used in vehicle catalysts and paraffin wax use (candles). The relevant pollutants are CO₂, CH₄, N₂O, NMVOC, particles (TSP, PM₁₀, PM_2.5), CO, PCDD/F and PAH.

• E. Electronics Industry; includes fibre optics. The relevant pollutants are HCB and PCBs.

• F. Product Uses as Substitutes for Ozone Depleting Substances; includes refrigeration, stationary and mobile air conditioning, foam blowing agents, aerosols and solvents. The relevant pollutants are HCB and PCBs.

• G. Other Product Manufacture and Use; includes use of electrical equipment, use of running shoes, use of SF₆ in laboratories, production of double glazed windows, medical application of N₂O, propellant for pressure and aerosol products, use of other products (fireworks, tobacco and charcoal for barbeques), food & beverages industry, wood processing and slaughterhouse waste. The relevant pollutants are CO₂, CH₄, N₂O, SF₆, NO_x, NMVOC, SO₂, NH₃, particles (TSP, PM₁₀, PM_2.5), CO, heavy metals (Pb, Cd, Hg, As, Cr, Cu, Ni, Se, Zn), PCDD/F, PAH, HCB and PCB.

 The most important pollutants in the IPPU sector in 2022 are greenhouse gases (GHG) (especially CO₂ and F-gasses), NMVOC, SO₂, PM_2.5 and some heavy metals. The IPPU sector makes up 3.4 % of the total national emission of greenhouse gasses (incl. LULUCF); hereof 5.0 % of the CO₂ emission and all of the F-gas emissions. The corresponding percentage for NMVOC, SO₂ and PM_2.5 are 24.6 %, 10.7 % and 7.2 %. A full list of the pollutants emitted from the IPPU sector with total 2022 emissions and the fraction of these emissions in relation to total national emissions are available in the linked Table 1.  The following figures present the distribution of GHG, NMVOC, SO₂ and PM_2.5 emissions respectively on the individual subsectors in 2022.  

Figure 1   Distribution of the emissions from the IPPU sector.

For greenhouse gasses, the largest single source is cement production (A.1) with 1073 kt CO₂ (64 % of total IPPU GHG emission), the second largest is refrigeration and air conditioning (F.1) with 250 kt CO₂e (15 % of total IPPU GHG emission). 

NMVOC emissions in the IPPU sector are primarily caused be solvent use (26.9 kt, i.e. 92 % of IPPU), a smaller share from the food & beverages industry (2.2 kt, i.e. 7.4 %) and minor contributions from mineral industries, chemical industries, metal industries and other product uses. The largest categories for solvent use are Other solvent use (D.3i) (16.4 kt NMVOC), Chemical products (D.3g) (4.7 kt) and Domestic solvent use including fungicides (D.3a) (3.3 kt).

Six sources contribute to the SO₂ emission in 2022. In mineral industries are contributions from production of ceramics (A.4a) (0.5 kt), stone wool production (A.4d) (0.02 kt) and glass production (A.3) (0.2 kt). In addition are contributions from production of catalysts (B.10) (0.1 kt), lead production (C.5) (0.2 kt) and use of other products (G.4) (0.04 kt).

For PM_2.5 emissions, the largest contributing sources are quarrying and mining of minerals other than coal (A.5a) with 0.15 kt (18 %), construction & demolition (A.5b) with 0.10 kt (13 %) and use of other products (G.4) with 0.27 kt (34 %) (primarily caused by the use of fireworks).

The trends of the individual greenhouse gasses along with the total GHG emission are presented in Figure 2. The decrease in emission of CO₂ in 2008-2009 may be explained by the decrease in economic activity.   

Figure 2   Total greenhouse gas emission and emission of the individual greenhouse gasses from the IPPU sector, and total emission and emission from individual sources for NMVOC, SO₂ and PM_2.5.

NMVOCs are not considered direct greenhouse gases, but their role as precursors in tropospheric ozone formation, which is a greenhouse gas, justifies their inclusion in a greenhouse gas inventory. Although the indirect CO₂ contribution from NMVOC is relatively small compared to e.g. CO₂ from carbonate use, the emissions are included in the national GHG emission inventories as CO₂.

The main source of NMVOC emissions in the IPPU sector is solvent use. Solvents are chemical compounds which are used on a global scale in industrial processes and as constituents in final products to dissolve e.g. paint, cosmetics, adhesives, ink, rubber, plastic, pesticides and aerosols. The most abundantly used NMVOC as solvent are ethanol, turpentine (white spirit defined as a mixture of stoddard solvent and solvent naphtha) and propylalcohol. Ethanol is used as solvent in the chemical industry and as windscreen washing agent. Turpentine is used as thinner for paints, lacquers and adhesives. Propylalcohol is used in cleaning agents in the manufacture of electrical equipment, flux agents for soldering, as solvent and thinner and as windscreen washing agent. Household emissions are dominated by propane and butane, which are used as aerosols in spray cans, primarily in cosmetics.

Emission of SO₂ is mainly caused by the production of ceramics; between 0.5 kt in 2022 (59 %) and 5.0 kt in 2007 (92 %). The fluctuations in the SO₂ emission during the time series are primarily caused by variations in the building/construction activities and the strong decline in emissions from 2007-2009 is due to the economic recession caused by the global financial crisis.

The vast majority of nitrous oxide emissions (98 % in average) were caused by nitric acid production, the emissions therefore decreased drastically when the singular production site closed down in 2004. This shut down also caused a significant decrease in particle emissions. While PM_2.5 emissions from construction and demolition have been increasing (until the years of the global financial crisis) emissions from glass production and steel production (due to the closing of the one Danish electro steelwork in 2005) have been decreasing. 

Emissions from the IPPU sector are calculated based on information given in annual environmental reports/PRTR, through contact with the companies, national statistics and modelling. Also, activity data and emissions from the EU Emission Trading Scheme (EU ETS) are used. International literature or default values given in international inventory guidelines (IPCC Guidelines and EMEP/EEA Emission Inventory Guidebook) are used where no country specific data are available.

For more information on the methodology and data used in the inventory of emissions of industrial processes, see the latest sector report Danish Emission Inventory for Industrial Processes and Annexes.